Problem:
After I upgraded to Mac OS Mountain Lion: My MacBook suddenly took much longer to become operational again after I opened its lid...
Solution:
In terminal or iTerm enter the following:
sudo pmset -a standbydelay 50000
Explanation:
This sets the delay from the default 4200 seconds up to 50.000 (more than 13 hours)
The OS has two different hibernation / sleep modes: one preserves the whole RAM content during sleep (which makes wakeup a breeze), the other stores RAM content on disk or SSD (which, in case of several GByte RAM, will need 10 secs and more to wake).
References:
Thanx to some discussion on apple.stackexchange
In case you want to learn more about hibernation and power management - consult the reference documentation.